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Open Control Panel > Network and Sharing Center > Change adapter settings. Right-click your Wi-Fi connection > Status > Wireless Properties > Security tab.
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Open Command Prompt as admin and type netsh wlan show profiles to see saved networks. Use netsh wlan show profile name="NETWORK_NAME" key=clear to view the password.
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If connected to Wi-Fi, go to Control Panel > Network and Sharing Center. Click on your Wi-Fi connection and select "Wireless Properties" to reveal the password.
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